MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin
Abstract In spite of greater efforts to address antibiotic resistance, Ciprofloxacin (CIP) buildup in the aqueous medium continues to rise. The negative effects of CIP on the environment can be minimized through a comprehensive understanding of the technological advancements in removal techniques. T...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-01-01
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| Series: | Macromolecular Materials and Engineering |
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| Online Access: | https://doi.org/10.1002/mame.202400238 |
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| author | Sriyanjali Bathula Swathi Thottathil Yashoda Malgar Puttaiahgowda |
| author_facet | Sriyanjali Bathula Swathi Thottathil Yashoda Malgar Puttaiahgowda |
| author_sort | Sriyanjali Bathula |
| collection | DOAJ |
| description | Abstract In spite of greater efforts to address antibiotic resistance, Ciprofloxacin (CIP) buildup in the aqueous medium continues to rise. The negative effects of CIP on the environment can be minimized through a comprehensive understanding of the technological advancements in removal techniques. The exploration of adsorbents like metal–organic frameworks (MOFs), activated carbon, porous organic polymers, etc., have found major usage in the adsorptive removal of antibiotics to tackle contamination. This study aims to compare the MOF‐based adsorbents and provide a guide to developing such materials for the successful removal of CIP. The isotherm models of the adsorbents are studied using Langmuir, Freundlich, Temkin, and Sips isotherms. Furthermore, pseudo‐second‐order, pseudo‐first order, intra‐particle diffusion, and Elovich models are used to study the kinetic models. The major mechanisms of adsorption, such as π–π interactions, H‐bonding, electrostatic interactions, hydrophobic interactions, and pore filling, are also analyzed. This study contributes to the future scope for the development of these MOFs for further exploration and applications in environmental remediation. |
| format | Article |
| id | doaj-art-66d17bad720d4701bec501bde7724cbc |
| institution | Kabale University |
| issn | 1438-7492 1439-2054 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Macromolecular Materials and Engineering |
| spelling | doaj-art-66d17bad720d4701bec501bde7724cbc2025-01-13T15:24:25ZengWiley-VCHMacromolecular Materials and Engineering1438-74921439-20542025-01-013101n/an/a10.1002/mame.202400238MOFs and MOF‐Based Composites for the Adsorptive Removal of CiprofloxacinSriyanjali Bathula0Swathi Thottathil1Yashoda Malgar Puttaiahgowda2Department of Chemical Engineering Manipal Institute of Technology Manipal Academy of Higher Education Manipal 576104 IndiaDepartment of Chemistry Manipal Institute of Technology Manipal Academy of Higher Education Manipal 576104 IndiaDepartment of Chemistry Manipal Institute of Technology Manipal Academy of Higher Education Manipal 576104 IndiaAbstract In spite of greater efforts to address antibiotic resistance, Ciprofloxacin (CIP) buildup in the aqueous medium continues to rise. The negative effects of CIP on the environment can be minimized through a comprehensive understanding of the technological advancements in removal techniques. The exploration of adsorbents like metal–organic frameworks (MOFs), activated carbon, porous organic polymers, etc., have found major usage in the adsorptive removal of antibiotics to tackle contamination. This study aims to compare the MOF‐based adsorbents and provide a guide to developing such materials for the successful removal of CIP. The isotherm models of the adsorbents are studied using Langmuir, Freundlich, Temkin, and Sips isotherms. Furthermore, pseudo‐second‐order, pseudo‐first order, intra‐particle diffusion, and Elovich models are used to study the kinetic models. The major mechanisms of adsorption, such as π–π interactions, H‐bonding, electrostatic interactions, hydrophobic interactions, and pore filling, are also analyzed. This study contributes to the future scope for the development of these MOFs for further exploration and applications in environmental remediation.https://doi.org/10.1002/mame.202400238AdsorptionCiprofloxacinEnvironmental remediationMOFs and MOF‐compositesWastewater treatment |
| spellingShingle | Sriyanjali Bathula Swathi Thottathil Yashoda Malgar Puttaiahgowda MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin Macromolecular Materials and Engineering Adsorption Ciprofloxacin Environmental remediation MOFs and MOF‐composites Wastewater treatment |
| title | MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin |
| title_full | MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin |
| title_fullStr | MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin |
| title_full_unstemmed | MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin |
| title_short | MOFs and MOF‐Based Composites for the Adsorptive Removal of Ciprofloxacin |
| title_sort | mofs and mof based composites for the adsorptive removal of ciprofloxacin |
| topic | Adsorption Ciprofloxacin Environmental remediation MOFs and MOF‐composites Wastewater treatment |
| url | https://doi.org/10.1002/mame.202400238 |
| work_keys_str_mv | AT sriyanjalibathula mofsandmofbasedcompositesfortheadsorptiveremovalofciprofloxacin AT swathithottathil mofsandmofbasedcompositesfortheadsorptiveremovalofciprofloxacin AT yashodamalgarputtaiahgowda mofsandmofbasedcompositesfortheadsorptiveremovalofciprofloxacin |