Herstellung und Charakterisierung der «Cyclothiadi(selenazenium)»-Kationen [Se2N2S]22⊕, [XSe2N2S]⊕ und [Se2N2S]2⊕

Bis(sulfinylamido)selenium, prepared from Se2Cl2 and (CH3)3SiNSO, forms with MF5 (molar ratio 1:1) in SO2 salts of the dimeric so-called cyclothiadi(selenazenium) cation  [Se2N2S]22⊕(MF6⊖)2 (1a: M = As; 1b: M = Sb; 1c: M = Nb). When the compounds 1a and 1c are treated with Cl2 or 1a with Br2 the co...

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Bibliographic Details
Main Authors: Alois Haas, Jörg Kasprowski
Format: Article
Language:deu
Published: Swiss Chemical Society 1988-10-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9872
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