Steric Effects on Reaction Rates Correlation Analysis of Solvolysis Data for Tertiary Carbon Substrates
Rate constants for solvolysis of tertiary chlorides and p-nitrobenzoates are compared and converted to Bentley’s unified reactivity scale. For the majority of structures consistent behavior is observed. Deviations are interpreted in terms of F-strain dr, to a minor extent, of leaving group hindranc...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1987-11-01
|
| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9818 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|