Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation

Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation

A 12-membered pyridinophane scaffold containing two pyridine and two tertiary amine residues is examined as a prototype ligand (<sup>tBu</sup>N4) for supporting nitrene transfer to olefins. The known [(<sup>tBu</sup>N4)M<sup>II</sup>(MeCN)<sub>2</sub>]...

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Bibliographic Details
Main Authors: Himanshu Bhatia, Lillian P. Adams, Ingrid Cordsiemon, Suraj Kumar Sahoo, Amitava Choudhury, Thomas R. Cundari, Pericles Stavropoulos
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Molecules
Subjects:
nitrene transfer
pyridine-containing macrocycles
aziridination
olefins
copper nitrenes
electrophilicity
Online Access:https://www.mdpi.com/1420-3049/30/15/3097
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