Strong Antiferromagnetic Interactions in the Binuclear Cobalt(II) Complex with a Bridged Nitroxide Diradical

Strong Antiferromagnetic Interactions in the Binuclear Cobalt(II) Complex with a Bridged Nitroxide Diradical

A binuclear cobalt–radical complex formed by the reaction of Co(hfac)<sub>2</sub>·2H<sub>2</sub>O (hfac = hexafluoroacetylacetonate) with the 2,2-bis(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolinyl) biradical (BR) has been synthesized. The complex {(hfac)Co<sup>II</su...

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Bibliographic Details
Main Authors: Vitaly A. Morozov, Eugenia V. Peresypkina, Wolfgang Wernsdorfer, Kira E. Vostrikova
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Magnetochemistry
Subjects:
nitroxyl radical
diradical
cobalt(II) complex
strong magnetic coupling
spin frustration
Online Access:https://www.mdpi.com/2312-7481/10/11/82
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