Enantioselective synthesis of planar chiral ferrocenes via gold(I)-catalyzed hydroarylation of N-ferrocenyl propiolamides

Enantioselective synthesis of planar chiral ferrocenes via gold(I)-catalyzed hydroarylation of N-ferrocenyl propiolamides

Herein, we report an intramolecular 6-endo-dig cyclization of N-ferrocenyl propiolamides for the synthesis of planar chiral ferrocenes enabled by gold(I)-catalyzed hydroarylation. By using this protocol, a variety of planar chiral ferrocenopyridin-2(1H)-ones were obtained in good yields and excellen...

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Bibliographic Details
Main Authors: Qian Zhou, Lulin Qiao, An-An Zhang, Lu Li, Tuan-Jie Meng, Baomin Fan, Yuan-Yuan Gao, Lantao Liu
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-05-01
Series:Green Synthesis and Catalysis
Subjects:
Planar chiral ferrocenes
Enantioselective synthesis
Gold(I)-catalyzed hydroarylation
6-endo-dig cyclization
N-ferrocenyl propiolamides
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554924000279
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