[VIV18O42H9(VVO4)]6⊖ und [VlV12VV6O42(SO4)]8⊖, zwei neuartige «Heteropolyanionen» gleicher Cluster-Struktur mit stark unterschiedlicher Elektronenpopulation
The two compounds Na6[VIV18O42H9(VVO4)]∙21 H2O (1) and (NH4)8[VlV12VV6O42(SO4)]∙25 H2O (2) have been prepared and characterized by X-ray structure analysis. Both anions exhibit a large difference in the electron population of their V18O42 cluster shells.
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1988-09-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9868 |
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