Structural Rearrangement in Cyclic Cu(II) Pyridyltriazole Complexes: Oxidation of Dabco to Oxalate and CO<sub>2</sub> Conversion to Carbonate

Structural Rearrangement in Cyclic Cu(II) Pyridyltriazole Complexes: Oxidation of Dabco to Oxalate and CO<sub>2</sub> Conversion to Carbonate

Structural rearrangements in metal–organic supramolecules constructed from the coordination of Cu(II) with <i>m</i>-xpt (<i>m</i>-xylylenebis(pyridyltriazole)) are investigated upon their interaction with 1,4-diazabicyclo[2.2.2]octane (dabco) and carbon dioxide-enriched air....

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Bibliographic Details
Main Authors: Uttam R. Pokharel, Frank R. Fronczek, Andrew W. Maverick
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Molecules
Subjects:
rearrangements
metal–organic supramolecules
dabco
carbonate and oxalate bridges
copper(II) complexes
pyridyltriazole
Online Access:https://www.mdpi.com/1420-3049/30/7/1430
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