AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants

A series of AgBr/TiO2 visible photocatalysts with heterojunction structure was synthesized using Ti(OC4H9)4, KBr, and AgNO3 as precursors. The phase composition, particle morphology and size, microstructures, and absorbance of these photocatalysts were characterized by X-ray diffraction, transmissio...

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Main Authors: Jianjun Liu, Yingchun Yu, Zhixin Liu, Shengli Zuo, Baoshan Li
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/254201
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author Jianjun Liu
Yingchun Yu
Zhixin Liu
Shengli Zuo
Baoshan Li
author_facet Jianjun Liu
Yingchun Yu
Zhixin Liu
Shengli Zuo
Baoshan Li
author_sort Jianjun Liu
collection DOAJ
description A series of AgBr/TiO2 visible photocatalysts with heterojunction structure was synthesized using Ti(OC4H9)4, KBr, and AgNO3 as precursors. The phase composition, particle morphology and size, microstructures, and absorbance of these photocatalysts were characterized by X-ray diffraction, transmission electron microscope (TEM), high-resolution TEM, and UV-vis spectra. It was found that the coupled AgBr/TiO2 was an effective photocatalyst to degrade the methylene blue under visible light irradiation, compared with the other noncoupled photocatalysts of AgBr, AgBr/P25, and P25. The photocatalytic activities of AgBr/TiO2 increase first and then decrease with increasing the mass ratio of mAgNO3/mTiO2 and the photocatalyst with the mass ratio of 3.35 has the highest photocatalytic activity. The results showed that the coupled photocatalyst has the particle size of about 15 nm with homogeneous dispersion and has the strongest absorption in whole UV-vis light region (250∼800 nm) originated from the synergetic effect of heterostructured AgBr/TiO2. The coupled AgBr/TiO2 photocatalyst can keep stable photocatalytic activity after five-circle runs.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2012-01-01
publisher Wiley
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series International Journal of Photoenergy
spelling doaj-art-53d793a12add435e971b3302c357a7da2025-02-03T01:08:59ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/254201254201AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye PollutantsJianjun Liu0Yingchun Yu1Zhixin Liu2Shengli Zuo3Baoshan Li4State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaA series of AgBr/TiO2 visible photocatalysts with heterojunction structure was synthesized using Ti(OC4H9)4, KBr, and AgNO3 as precursors. The phase composition, particle morphology and size, microstructures, and absorbance of these photocatalysts were characterized by X-ray diffraction, transmission electron microscope (TEM), high-resolution TEM, and UV-vis spectra. It was found that the coupled AgBr/TiO2 was an effective photocatalyst to degrade the methylene blue under visible light irradiation, compared with the other noncoupled photocatalysts of AgBr, AgBr/P25, and P25. The photocatalytic activities of AgBr/TiO2 increase first and then decrease with increasing the mass ratio of mAgNO3/mTiO2 and the photocatalyst with the mass ratio of 3.35 has the highest photocatalytic activity. The results showed that the coupled photocatalyst has the particle size of about 15 nm with homogeneous dispersion and has the strongest absorption in whole UV-vis light region (250∼800 nm) originated from the synergetic effect of heterostructured AgBr/TiO2. The coupled AgBr/TiO2 photocatalyst can keep stable photocatalytic activity after five-circle runs.http://dx.doi.org/10.1155/2012/254201
spellingShingle Jianjun Liu
Yingchun Yu
Zhixin Liu
Shengli Zuo
Baoshan Li
AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
International Journal of Photoenergy
title AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
title_full AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
title_fullStr AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
title_full_unstemmed AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
title_short AgBr-Coupled TiO2: A Visible Heterostructured Photocatalyst for Degrading Dye Pollutants
title_sort agbr coupled tio2 a visible heterostructured photocatalyst for degrading dye pollutants
url http://dx.doi.org/10.1155/2012/254201
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AT yingchunyu agbrcoupledtio2avisibleheterostructuredphotocatalystfordegradingdyepollutants
AT zhixinliu agbrcoupledtio2avisibleheterostructuredphotocatalystfordegradingdyepollutants
AT shenglizuo agbrcoupledtio2avisibleheterostructuredphotocatalystfordegradingdyepollutants
AT baoshanli agbrcoupledtio2avisibleheterostructuredphotocatalystfordegradingdyepollutants