Ketoins from Primary Alkylhalides, Grignard Compounds and Carbonmonoxide in Ether-HMPT
Whereas carbonylation of primary Grignard compounds in ether-HMPT leads to ketones 1, reaction in the presence of an additional amount of alkylhalide results in the formation of hydroxyketones 2 and 3. When using neat HMPT as solvent, 2 is the main product (up to 55 % yield).
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| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1976-03-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9303 |
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