Guanine-based spin valve with spin rectification effect for an artificial memory element

Non-volatile electronic memory elements are very attractive for applications, not only for information storage but also in logic circuits, sensing devices and neuromorphic computing. Here, a ferroelectric film of guanine nucleobase is used in a resistive memory junction sandwiched between two differ...

Full description

Saved in:
Bibliographic Details
Main Authors: Nicusor Iacob, Cristina Chirila, Mama Sangaré, Andrei Kuncser, Anda E. Stanciu, Marcela Socol, Catalin C. Negrila, Mihaela Botea, Claudiu Locovei, Gabriel Schinteie, Aurelian C. Galca, Anca Stanculescu, Lucian Pintilie, Victor Kuncser, Bogdana Borca
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844024172027
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841526192865280000
author Nicusor Iacob
Cristina Chirila
Mama Sangaré
Andrei Kuncser
Anda E. Stanciu
Marcela Socol
Catalin C. Negrila
Mihaela Botea
Claudiu Locovei
Gabriel Schinteie
Aurelian C. Galca
Anca Stanculescu
Lucian Pintilie
Victor Kuncser
Bogdana Borca
author_facet Nicusor Iacob
Cristina Chirila
Mama Sangaré
Andrei Kuncser
Anda E. Stanciu
Marcela Socol
Catalin C. Negrila
Mihaela Botea
Claudiu Locovei
Gabriel Schinteie
Aurelian C. Galca
Anca Stanculescu
Lucian Pintilie
Victor Kuncser
Bogdana Borca
author_sort Nicusor Iacob
collection DOAJ
description Non-volatile electronic memory elements are very attractive for applications, not only for information storage but also in logic circuits, sensing devices and neuromorphic computing. Here, a ferroelectric film of guanine nucleobase is used in a resistive memory junction sandwiched between two different ferromagnetic films of Co and CoCr alloys. The magnetic films have an in-plane easy axis of magnetization and different coercive fields whereas the guanine film ensures a very long spin transport length, at 100 K. The non-volatile resistance states of the multiferroic spintronic junction with two-terminals are manipulated by a combined action of small external magnetic and electric fields. Thus, the magnetic field controls the relative orientation of the magnetization of the metallic ferromagnetic electrodes, that leads to different magnetoresistance states. The orientation and the magnitude of the electric field controls the orientation of the polarization of the guanine ferroelectric barrier, that leads to different electroresistance states, respectively. Moreover, we have observed a strong interfacial coupling of the two parameters. Consequently, positive and negative magnetoresistance hysteresis loops corresponding to spin rectification effects and non-hysteretic (erased) resistive states are manipulated with the electric field by switching the orientation of the electrical polarization of the organic ferroelectric.
format Article
id doaj-art-50a87f0d5a40498f8ba36656531174a5
institution Kabale University
issn 2405-8440
language English
publishDate 2025-01-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj-art-50a87f0d5a40498f8ba36656531174a52025-01-17T04:50:24ZengElsevierHeliyon2405-84402025-01-01111e41171Guanine-based spin valve with spin rectification effect for an artificial memory elementNicusor Iacob0Cristina Chirila1Mama Sangaré2Andrei Kuncser3Anda E. Stanciu4Marcela Socol5Catalin C. Negrila6Mihaela Botea7Claudiu Locovei8Gabriel Schinteie9Aurelian C. Galca10Anca Stanculescu11Lucian Pintilie12Victor Kuncser13Bogdana Borca14National Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, Romania; Institute of Applied Sciences, University of Sciences, Techniques and Technology of Bamako (USTTB), Bamako, MaliNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, RomaniaNational Institute of Materials Physics, 077125 Magurele, Ilfov, Romania; Corresponding author.Non-volatile electronic memory elements are very attractive for applications, not only for information storage but also in logic circuits, sensing devices and neuromorphic computing. Here, a ferroelectric film of guanine nucleobase is used in a resistive memory junction sandwiched between two different ferromagnetic films of Co and CoCr alloys. The magnetic films have an in-plane easy axis of magnetization and different coercive fields whereas the guanine film ensures a very long spin transport length, at 100 K. The non-volatile resistance states of the multiferroic spintronic junction with two-terminals are manipulated by a combined action of small external magnetic and electric fields. Thus, the magnetic field controls the relative orientation of the magnetization of the metallic ferromagnetic electrodes, that leads to different magnetoresistance states. The orientation and the magnitude of the electric field controls the orientation of the polarization of the guanine ferroelectric barrier, that leads to different electroresistance states, respectively. Moreover, we have observed a strong interfacial coupling of the two parameters. Consequently, positive and negative magnetoresistance hysteresis loops corresponding to spin rectification effects and non-hysteretic (erased) resistive states are manipulated with the electric field by switching the orientation of the electrical polarization of the organic ferroelectric.http://www.sciencedirect.com/science/article/pii/S2405844024172027Guanine nucleobaseMultiferroic junctionOrganic ferroelectricSpin valveElectroresistanceMagnetoresistance
spellingShingle Nicusor Iacob
Cristina Chirila
Mama Sangaré
Andrei Kuncser
Anda E. Stanciu
Marcela Socol
Catalin C. Negrila
Mihaela Botea
Claudiu Locovei
Gabriel Schinteie
Aurelian C. Galca
Anca Stanculescu
Lucian Pintilie
Victor Kuncser
Bogdana Borca
Guanine-based spin valve with spin rectification effect for an artificial memory element
Heliyon
Guanine nucleobase
Multiferroic junction
Organic ferroelectric
Spin valve
Electroresistance
Magnetoresistance
title Guanine-based spin valve with spin rectification effect for an artificial memory element
title_full Guanine-based spin valve with spin rectification effect for an artificial memory element
title_fullStr Guanine-based spin valve with spin rectification effect for an artificial memory element
title_full_unstemmed Guanine-based spin valve with spin rectification effect for an artificial memory element
title_short Guanine-based spin valve with spin rectification effect for an artificial memory element
title_sort guanine based spin valve with spin rectification effect for an artificial memory element
topic Guanine nucleobase
Multiferroic junction
Organic ferroelectric
Spin valve
Electroresistance
Magnetoresistance
url http://www.sciencedirect.com/science/article/pii/S2405844024172027
work_keys_str_mv AT nicusoriacob guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT cristinachirila guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT mamasangare guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT andreikuncser guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT andaestanciu guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT marcelasocol guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT catalincnegrila guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT mihaelabotea guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT claudiulocovei guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT gabrielschinteie guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT aureliancgalca guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT ancastanculescu guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT lucianpintilie guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT victorkuncser guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement
AT bogdanaborca guaninebasedspinvalvewithspinrectificationeffectforanartificialmemoryelement