Efficient Synthesis of Eight-Membered Cyclic Diaryl Sulfides via an Aryne Reaction with 2-Methylenebenzothiophene-3-Ones
In this study, we develop a concise and efficient synthetic strategy for the construction of eight-membered cyclic diaryl sulfides by undertaking [3+2] cycloaddition, 1,2-hydrogen shift, and C(sp<sup>2</sup>)-S bond cleavage steps on 2-methylenebenzothiophene-3-ones with aryne, using TBA...
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| Main Authors: | Juhua Feng, Wenjie Zou, Haokun Zhang, Qilin Huang, Ailin Huang, Kuan Liu, Guizhou Yue |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-05-01
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| Series: | Reactions |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2624-781X/6/2/35 |
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