Efficient Synthesis of Eight-Membered Cyclic Diaryl Sulfides via an Aryne Reaction with 2-Methylenebenzothiophene-3-Ones

Efficient Synthesis of Eight-Membered Cyclic Diaryl Sulfides via an Aryne Reaction with 2-Methylenebenzothiophene-3-Ones

In this study, we develop a concise and efficient synthetic strategy for the construction of eight-membered cyclic diaryl sulfides by undertaking [3+2] cycloaddition, 1,2-hydrogen shift, and C(sp<sup>2</sup>)-S bond cleavage steps on 2-methylenebenzothiophene-3-ones with aryne, using TBA...

Full description

Saved in:
Bibliographic Details
Main Authors: Juhua Feng, Wenjie Zou, Haokun Zhang, Qilin Huang, Ailin Huang, Kuan Liu, Guizhou Yue
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Reactions
Subjects:
aryne
[3+2] cycloaddition
eight-membered cyclic diaryl sulfides
2-methylenebenzothiophene-3-ones
Online Access:https://www.mdpi.com/2624-781X/6/2/35
Tags: Add Tag
No Tags, Be the first to tag this record!

Internet

https://www.mdpi.com/2624-781X/6/2/35

Similar Items