Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells

Green synthesis of metal oxides has attracted attention as the latest technology in synthesizing metal oxide nanoparticles due to its simplicity, cheapness, non-toxicity and its ability for large scale production. Metal oxides find applications in dye sensitized solar cells (DSSCs) as counter elect...

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Main Authors: Emma Panzi Mukhokosi, Stephen Tenywa, Nandipha L. Bothab, Shohreh Azizi, Mathapelo Pearl Seopela, Malik Maaza
Format: Article
Language:English
Published: Nigerian Society of Physical Sciences 2025-02-01
Series:Journal of Nigerian Society of Physical Sciences
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Online Access:https://journal.nsps.org.ng/index.php/jnsps/article/view/2309
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author Emma Panzi Mukhokosi
Stephen Tenywa
Nandipha L. Bothab
Shohreh Azizi
Mathapelo Pearl Seopela
Malik Maaza
author_facet Emma Panzi Mukhokosi
Stephen Tenywa
Nandipha L. Bothab
Shohreh Azizi
Mathapelo Pearl Seopela
Malik Maaza
author_sort Emma Panzi Mukhokosi
collection DOAJ
description Green synthesis of metal oxides has attracted attention as the latest technology in synthesizing metal oxide nanoparticles due to its simplicity, cheapness, non-toxicity and its ability for large scale production. Metal oxides find applications in dye sensitized solar cells (DSSCs) as counter electrodes (CEs) and photo-anodes. However, applications of green synthesized metal oxides as counter electrodes have not been fully explored. In this study, CuO nanoparticles (NPs) were synthesized from Cucurbita maxima leaf extract and applied as a CE in DSSC. Uniformly synthesized CuO NPs were subjected to various characterization tools to obtain the crystal structure, surface morphology, particle size, optical properties, chemical bonds and photovoltaic properties. Using a natural dye from of Cucurbita maxima as a photon absorber, a short circuit current density ( Jsc) of 4.2 µA/cm2, open circuit voltage (Voc) of 0.17 V, a maximum power (Pmax) of 0.18 mW/cm2, and a power conversion efficiency (PCE) of 1.8 × 10?4 % under one-sun illumination were obtained.
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institution Kabale University
issn 2714-2817
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language English
publishDate 2025-02-01
publisher Nigerian Society of Physical Sciences
record_format Article
series Journal of Nigerian Society of Physical Sciences
spelling doaj-art-4f759d31ed4c441e8ab2b9f1e9272f5e2025-01-17T18:52:26ZengNigerian Society of Physical SciencesJournal of Nigerian Society of Physical Sciences2714-28172714-47042025-02-017110.46481/jnsps.2025.2309Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cellsEmma Panzi Mukhokosi0Stephen Tenywa1Nandipha L. Bothab2Shohreh Azizi3Mathapelo Pearl Seopela4Malik Maaza5Department of Physics, Faculty of Science, Kyambogo University, PO Box 1, Kampala, UgandaDepartment of Physics, Faculty of Science, Kyambogo University, PO Box 1, Kampala, UgandaCollege of Graduate Studies, UNESCO UNISA Africa Chair in Nanosciences & Nanotechnology, University of South Africa, Pretoria, South Africa Materials; Materials Research Department, Nanosciences African Network (NANOAFNET), iThemba LABS, PO Box 722, Cape Town, South AfricaCollege of Graduate Studies, UNESCO UNISA Africa Chair in Nanosciences & Nanotechnology, University of South Africa, Pretoria, South Africa Materials; Research Department, Nanosciences African Network (NANOAFNET), iThemba LABS, PO Box 722, Cape Town, South AfricaDepartment of Chemical Sciences, University of South Africa, Auckland Park Campus, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaCollege of Graduate Studies, UNESCO UNISA Africa Chair in Nanosciences & Nanotechnology, University of South Africa, Pretoria, South Africa; Materials Research Department, Nanosciences African Network (NANOAFNET), iThemba LABS, PO Box 722, Cape Town, South Africa Green synthesis of metal oxides has attracted attention as the latest technology in synthesizing metal oxide nanoparticles due to its simplicity, cheapness, non-toxicity and its ability for large scale production. Metal oxides find applications in dye sensitized solar cells (DSSCs) as counter electrodes (CEs) and photo-anodes. However, applications of green synthesized metal oxides as counter electrodes have not been fully explored. In this study, CuO nanoparticles (NPs) were synthesized from Cucurbita maxima leaf extract and applied as a CE in DSSC. Uniformly synthesized CuO NPs were subjected to various characterization tools to obtain the crystal structure, surface morphology, particle size, optical properties, chemical bonds and photovoltaic properties. Using a natural dye from of Cucurbita maxima as a photon absorber, a short circuit current density ( Jsc) of 4.2 µA/cm2, open circuit voltage (Voc) of 0.17 V, a maximum power (Pmax) of 0.18 mW/cm2, and a power conversion efficiency (PCE) of 1.8 × 10?4 % under one-sun illumination were obtained. https://journal.nsps.org.ng/index.php/jnsps/article/view/2309Green synthesisDSSCsCuOCucurbita maximaNatural dye
spellingShingle Emma Panzi Mukhokosi
Stephen Tenywa
Nandipha L. Bothab
Shohreh Azizi
Mathapelo Pearl Seopela
Malik Maaza
Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
Journal of Nigerian Society of Physical Sciences
Green synthesis
DSSCs
CuO
Cucurbita maxima
Natural dye
title Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
title_full Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
title_fullStr Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
title_full_unstemmed Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
title_short Green synthesis of CuO nanoparticles from Cucurbita maxima leaf extract; a platinum free counter electrode for dye sensitized solar cells
title_sort green synthesis of cuo nanoparticles from cucurbita maxima leaf extract a platinum free counter electrode for dye sensitized solar cells
topic Green synthesis
DSSCs
CuO
Cucurbita maxima
Natural dye
url https://journal.nsps.org.ng/index.php/jnsps/article/view/2309
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