EFFICIENT PHOSPHOROUS-SULFUR BOND REDUCTION IN BICYCLIC THIAPHOSPHORANES WITH TRI-n-BUTYLTIN HYDRIDE
High yield photolytic reduction of a series of thiaphosphoranes Z p SR to give Z p H with UV-light-induced tri-n-butyltin hydride through phosphoranyl radical Z p is described. This reaction is inhibited by a-methylstyrene and initiated by a radical initiator such as azobisisobutyronitrile
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
1993-03-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31155_6c00aa9e3719bab443a3ac66f2522b47.pdf |
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