Experimental Determination of Primary and Secondary Deuterium Isotope Effects in the FeI-Mediated CH/CC Bond Activation of [Fe(4-Heptanone)]⊕ Complexes in the Gas Phase
The gas-phase behaviour of [Fe(4-heptanone)]⊕ is in several aspects quite distinct from that of other Fe⊕ complexes as far as kinetic details of the individual steps of CH/CC bond activation are concerned. From the study of intramolecular kinetic isotope effects the following is concluded: (i) In t...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1989-10-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9926 |
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