Atomically precise copper clusters with dual sites for highly chemoselective and efficient hydroboration

Abstract The hydroboration of alkynes into vinylboronate esters is a vital transformation, but achieving high chemoselectivity of targeted functional groups and an appreciable turnover number is a considerable challenge. Herein, we develop two dynamically regulating dual-catalytic-site copper cluste...

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Bibliographic Details
Main Authors: Teng Jia, Jie Ai, Xiaoguang Li, Miao-Miao Zhang, Yue Hua, Yi-Xin Li, Cai-Fang Sun, Feng Liu, Ren-Wu Huang, Zheng Wang, Shuang-Quan Zang
Format: Article
Language:English
Published: Nature Portfolio 2024-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-53950-7
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