Trimethyl Orthobenzoate as a1-C1-Phenyl-Synthon for Functionalization of 3-Unsubstituted Indoles

The methylindoles 2a and 2b are regioselectively functionalized with trimethyl orthobenzoate at C-3 by means of proton catalysis. The first stage is the formation of the key compounds, 3-indolyl-phenyl-methoxycarbenium ions 3. These can then be dealkylated under mild conditions using nucleophilic s...

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Bibliographic Details
Main Authors: Ulf Pindur, Johann Müller
Format: Article
Language:deu
Published: Swiss Chemical Society 1985-05-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9660
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