Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation
The sonochemical oxidation of hydroxylamine in alkaline aqueous, aqueous-methanol and methanol solutions yielded peroxonitrite ion as a main product. A little nitrite and nitrate were also formed. The oxidation yield increased with methanol concentration in the solution. The mechanism of oxidation b...
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| Format: | Article |
| Language: | English |
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Institute of Fundamental Technological Research Polish Academy of Sciences
2015-07-01
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| Series: | Archives of Acoustics |
| Online Access: | https://acoustics.ippt.pan.pl/index.php/aa/article/view/3050 |
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| author | Andrzej JANOWSKI Jadwiga RZESZOTARSKA |
| author_facet | Andrzej JANOWSKI Jadwiga RZESZOTARSKA |
| author_sort | Andrzej JANOWSKI |
| collection | DOAJ |
| description | The sonochemical oxidation of hydroxylamine in alkaline aqueous, aqueous-methanol and methanol solutions yielded peroxonitrite ion as a main product. A little nitrite and nitrate were also formed. The oxidation yield increased with methanol concentration in the solution. The mechanism of oxidation both in aqueous solution and in the presence of alcohol is discussed. |
| format | Article |
| id | doaj-art-3fe4e70ce93e4b7e84f3c8ed7d7d6f23 |
| institution | Kabale University |
| issn | 0137-5075 2300-262X |
| language | English |
| publishDate | 2015-07-01 |
| publisher | Institute of Fundamental Technological Research Polish Academy of Sciences |
| record_format | Article |
| series | Archives of Acoustics |
| spelling | doaj-art-3fe4e70ce93e4b7e84f3c8ed7d7d6f232025-08-20T03:27:56ZengInstitute of Fundamental Technological Research Polish Academy of SciencesArchives of Acoustics0137-50752300-262X2015-07-01143-4Liquid-phase oxidation of hydroxylamine with ultrasonic irradiationAndrzej JANOWSKI0Jadwiga RZESZOTARSKA1University of WarsawUniversity of WarsawThe sonochemical oxidation of hydroxylamine in alkaline aqueous, aqueous-methanol and methanol solutions yielded peroxonitrite ion as a main product. A little nitrite and nitrate were also formed. The oxidation yield increased with methanol concentration in the solution. The mechanism of oxidation both in aqueous solution and in the presence of alcohol is discussed.https://acoustics.ippt.pan.pl/index.php/aa/article/view/3050 |
| spellingShingle | Andrzej JANOWSKI Jadwiga RZESZOTARSKA Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation Archives of Acoustics |
| title | Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation |
| title_full | Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation |
| title_fullStr | Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation |
| title_full_unstemmed | Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation |
| title_short | Liquid-phase oxidation of hydroxylamine with ultrasonic irradiation |
| title_sort | liquid phase oxidation of hydroxylamine with ultrasonic irradiation |
| url | https://acoustics.ippt.pan.pl/index.php/aa/article/view/3050 |
| work_keys_str_mv | AT andrzejjanowski liquidphaseoxidationofhydroxylaminewithultrasonicirradiation AT jadwigarzeszotarska liquidphaseoxidationofhydroxylaminewithultrasonicirradiation |