Electrodeposition of alloys or compounds in molten salts and applications

This article deals with the different modes of preparation of alloys or intermetallic compounds using the electrodeposition in molten salts, more particularly molten alkali fluorides. The interest in this process is to obtain new materials for high technology, particularly the compounds of reactive...

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Main Authors: Taxil P., Chamelot P., Massot L., Hamel C.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2003-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302177T.pdf
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author Taxil P.
Chamelot P.
Massot L.
Hamel C.
author_facet Taxil P.
Chamelot P.
Massot L.
Hamel C.
author_sort Taxil P.
collection DOAJ
description This article deals with the different modes of preparation of alloys or intermetallic compounds using the electrodeposition in molten salts, more particularly molten alkali fluorides. The interest in this process is to obtain new materials for high technology, particularly the compounds of reactive components such as actinides, rare earth and refractory metals. Two ways of preparation are considered: (i) electrocoating of the more reactive metal on a cathode made of the noble one and reaction between the two metals in contact, and (ii) electrocoating on an inert cathode of the intermetallic compound by coreduction of the ions of each elements. The kinetic is controlled by the reaction at the electrolyte interface. A wide bibliographic survey on the preparation of various compounds (intermetallic compounds, borides, carbides…) is given and a special attention is paid to the own experience of the authors in the preparation of these compounds and interpretation of their results.
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institution Kabale University
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publishDate 2003-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-3f3b8784f71b4b84833a904dc74b9c342025-02-03T00:53:04ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392003-01-01391-217720010.2298/JMMB0302177TElectrodeposition of alloys or compounds in molten salts and applicationsTaxil P.Chamelot P.Massot L.Hamel C.This article deals with the different modes of preparation of alloys or intermetallic compounds using the electrodeposition in molten salts, more particularly molten alkali fluorides. The interest in this process is to obtain new materials for high technology, particularly the compounds of reactive components such as actinides, rare earth and refractory metals. Two ways of preparation are considered: (i) electrocoating of the more reactive metal on a cathode made of the noble one and reaction between the two metals in contact, and (ii) electrocoating on an inert cathode of the intermetallic compound by coreduction of the ions of each elements. The kinetic is controlled by the reaction at the electrolyte interface. A wide bibliographic survey on the preparation of various compounds (intermetallic compounds, borides, carbides…) is given and a special attention is paid to the own experience of the authors in the preparation of these compounds and interpretation of their results.http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302177T.pdfElectrosynthesisalloysintermetalliccompoundsmolten saltsalkalifluoridesco-reductionreactive electrodeposition
spellingShingle Taxil P.
Chamelot P.
Massot L.
Hamel C.
Electrodeposition of alloys or compounds in molten salts and applications
Journal of Mining and Metallurgy. Section B: Metallurgy
Electrosynthesis
alloys
intermetallic
compounds
molten salts
alkalifluorides
co-reduction
reactive electrodeposition
title Electrodeposition of alloys or compounds in molten salts and applications
title_full Electrodeposition of alloys or compounds in molten salts and applications
title_fullStr Electrodeposition of alloys or compounds in molten salts and applications
title_full_unstemmed Electrodeposition of alloys or compounds in molten salts and applications
title_short Electrodeposition of alloys or compounds in molten salts and applications
title_sort electrodeposition of alloys or compounds in molten salts and applications
topic Electrosynthesis
alloys
intermetallic
compounds
molten salts
alkalifluorides
co-reduction
reactive electrodeposition
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302177T.pdf
work_keys_str_mv AT taxilp electrodepositionofalloysorcompoundsinmoltensaltsandapplications
AT chamelotp electrodepositionofalloysorcompoundsinmoltensaltsandapplications
AT massotl electrodepositionofalloysorcompoundsinmoltensaltsandapplications
AT hamelc electrodepositionofalloysorcompoundsinmoltensaltsandapplications