(NH4)2Cd2Cl3F3 and (NH4)2Cd2Br3F3: The First Fluoride‐Containing d10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties

(NH4)2Cd2Cl3F3 and (NH4)2Cd2Br3F3: The First Fluoride‐Containing d10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties

Abstract In the search for new ultraviolet (UV) nonlinear optical (NLO) materials, two novel cadmium mixed halide compounds, (NH4)2Cd2Cl3F3 and (NH4)2Cd2Br3F3, are successfully synthesized via hydrothermal methods. These compounds crystallize in the noncentrosymmetric (NCS) space group, R32, and are...

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Bibliographic Details
Main Authors: Seunghun Choi, Yang Li, Yunseung Kuk, Kang Min Ok
Format: Article
Language:English
Published: Wiley 2025-03-01
Series:Advanced Science
Subjects:
d10 metal systems
fluoride‐containing mixed halides
nonlinear optical materials
second‐harmonic generation
ultraviolet transparency
Online Access:https://doi.org/10.1002/advs.202414503
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https://doi.org/10.1002/advs.202414503

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