Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure
MIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe) make it a good candidate for potential applica...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/792827 |
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| author | Jing Shi Shengtao Hei Huanhuan Liu Yanghe Fu Fumin Zhang Yijun Zhong Weidong Zhu |
| author_facet | Jing Shi Shengtao Hei Huanhuan Liu Yanghe Fu Fumin Zhang Yijun Zhong Weidong Zhu |
| author_sort | Jing Shi |
| collection | DOAJ |
| description | MIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe) make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C) under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous) pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe) is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe) is synthesized by a facile low-temperature (<100°C) synthesis route at atmospheric pressure by reaction of metallic iron and trimesic acid in water. Due to our synthesis is conducted with agitation, higher MOF yield (>90%) still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically. |
| format | Article |
| id | doaj-art-3bfb79f884a44db6b3cb7c17f4055c9a |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-3bfb79f884a44db6b3cb7c17f4055c9a2025-02-03T01:12:26ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/792827792827Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric PressureJing Shi0Shengtao Hei1Huanhuan Liu2Yanghe Fu3Fumin Zhang4Yijun Zhong5Weidong Zhu6Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaKey Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, 321004 Jinhua, ChinaMIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe) make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C) under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous) pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe) is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe) is synthesized by a facile low-temperature (<100°C) synthesis route at atmospheric pressure by reaction of metallic iron and trimesic acid in water. Due to our synthesis is conducted with agitation, higher MOF yield (>90%) still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.http://dx.doi.org/10.1155/2013/792827 |
| spellingShingle | Jing Shi Shengtao Hei Huanhuan Liu Yanghe Fu Fumin Zhang Yijun Zhong Weidong Zhu Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure Journal of Chemistry |
| title | Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure |
| title_full | Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure |
| title_fullStr | Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure |
| title_full_unstemmed | Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure |
| title_short | Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure |
| title_sort | synthesis of mil 100 fe at low temperature and atmospheric pressure |
| url | http://dx.doi.org/10.1155/2013/792827 |
| work_keys_str_mv | AT jingshi synthesisofmil100featlowtemperatureandatmosphericpressure AT shengtaohei synthesisofmil100featlowtemperatureandatmosphericpressure AT huanhuanliu synthesisofmil100featlowtemperatureandatmosphericpressure AT yanghefu synthesisofmil100featlowtemperatureandatmosphericpressure AT fuminzhang synthesisofmil100featlowtemperatureandatmosphericpressure AT yijunzhong synthesisofmil100featlowtemperatureandatmosphericpressure AT weidongzhu synthesisofmil100featlowtemperatureandatmosphericpressure |