Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics

In this work, dense CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] ceramics were prepared by a conventional solid phase method. The effect of Al[Formula: see text]/Ta[Formula: see text] dopants on the dielectric properties of CdCu3Ti4O[Formula: see text] ce...

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Main Authors: Huan Liu, Zhanhui Peng, Yulin Chen, Bi Chen, Di Wu, Lingling Wei, Pengfei Liang, Xiaolian Chao, Zupei Yang
Format: Article
Language:English
Published: World Scientific Publishing 2025-02-01
Series:Journal of Advanced Dielectrics
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Online Access:https://www.worldscientific.com/doi/10.1142/S2010135X24400162
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author Huan Liu
Zhanhui Peng
Yulin Chen
Bi Chen
Di Wu
Lingling Wei
Pengfei Liang
Xiaolian Chao
Zupei Yang
author_facet Huan Liu
Zhanhui Peng
Yulin Chen
Bi Chen
Di Wu
Lingling Wei
Pengfei Liang
Xiaolian Chao
Zupei Yang
author_sort Huan Liu
collection DOAJ
description In this work, dense CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] ceramics were prepared by a conventional solid phase method. The effect of Al[Formula: see text]/Ta[Formula: see text] dopants on the dielectric properties of CdCu3Ti4O[Formula: see text] ceramics was systematically investigated. Upon Al[Formula: see text]/Ta[Formula: see text] co-doping, the dielectric properties of CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] were significantly enhanced. Particularly, the CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] material displays a decent dielectric property, where dielectric constants ([Formula: see text]), loss tangent (tan [Formula: see text]) at a test frequency of 1[Formula: see text]kHz are able to satisfy the application temperature requirement of the Y6R capacitor. Surprisingly, the refined grains resulting from Al[Formula: see text]/Ta[Formula: see text] co-doping lead to heightened resistance at grain boundaries, which is closely associated with enhanced dielectric properties. Meanwhile, the giant dielectric property of the materials can be attributed to the effect of the internal barrier layer capacitance. The obtained results are expected to provide a new idea for obtaining high dielectric constant and low loss tangent in CdCTO-based materials and promote the practical application of such materials.
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institution Kabale University
issn 2010-135X
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language English
publishDate 2025-02-01
publisher World Scientific Publishing
record_format Article
series Journal of Advanced Dielectrics
spelling doaj-art-34bedf32d95443ad8aeaa2af4c5a8ecc2025-01-06T00:55:10ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682025-02-01150110.1142/S2010135X24400162Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramicsHuan Liu0Zhanhui Peng1Yulin Chen2Bi Chen3Di Wu4Lingling Wei5Pengfei Liang6Xiaolian Chao7Zupei Yang8Key Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaKey Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaKey Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaSchool of Chemistry and Chemical Engineering, Yulin University, Xi’an 719000, Shaanxi, P. R. ChinaKey Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaSchool of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaSchool of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaKey Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaKey Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710062, Shaanxi, P. R. ChinaIn this work, dense CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] ceramics were prepared by a conventional solid phase method. The effect of Al[Formula: see text]/Ta[Formula: see text] dopants on the dielectric properties of CdCu3Ti4O[Formula: see text] ceramics was systematically investigated. Upon Al[Formula: see text]/Ta[Formula: see text] co-doping, the dielectric properties of CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] were significantly enhanced. Particularly, the CdCu3(Al[Formula: see text]Ta[Formula: see text]Ti[Formula: see text]O[Formula: see text] material displays a decent dielectric property, where dielectric constants ([Formula: see text]), loss tangent (tan [Formula: see text]) at a test frequency of 1[Formula: see text]kHz are able to satisfy the application temperature requirement of the Y6R capacitor. Surprisingly, the refined grains resulting from Al[Formula: see text]/Ta[Formula: see text] co-doping lead to heightened resistance at grain boundaries, which is closely associated with enhanced dielectric properties. Meanwhile, the giant dielectric property of the materials can be attributed to the effect of the internal barrier layer capacitance. The obtained results are expected to provide a new idea for obtaining high dielectric constant and low loss tangent in CdCTO-based materials and promote the practical application of such materials.https://www.worldscientific.com/doi/10.1142/S2010135X24400162CdCu3Ti4Odielectric constantloss tangentIBLC
spellingShingle Huan Liu
Zhanhui Peng
Yulin Chen
Bi Chen
Di Wu
Lingling Wei
Pengfei Liang
Xiaolian Chao
Zupei Yang
Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
Journal of Advanced Dielectrics
CdCu3Ti4O
dielectric constant
loss tangent
IBLC
title Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
title_full Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
title_fullStr Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
title_full_unstemmed Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
title_short Effect of (Al/Ta) co-doped on dielectric properties of CdCu3Ti4O ceramics
title_sort effect of al ta co doped on dielectric properties of cdcu3ti4o ceramics
topic CdCu3Ti4O
dielectric constant
loss tangent
IBLC
url https://www.worldscientific.com/doi/10.1142/S2010135X24400162
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