Synthesis and Circular Dichroism of 5- and 6-Halogenobicyclo[2.2.1]hept-5-en-2-ones; Tests for the Dekkers' Quantitative Chirality Rule
Stereoselective syntheses of (+)-(1R,4R)-5-chloro-, -5-bromo-, -6-chloro-, and -6-bromobicyclo[2.2.1]hept-5-en-2-ones ((+)-2-(+)-5) are presented. The chiroptical properties (CD spectra) of these halogenated derivatives are compared with those of the non-substituted (+)-(1R,4R)-bicyclo[2.2.1]hept-5...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1988-01-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9825 |
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