Initial Examinations of the Diastereoselectivity and Chemoselectivity of Intramolecular Silyl Nitronate [3+2] Cycloadditions with Alkenyl/Alkynyl Nitroethers

Initial Examinations of the Diastereoselectivity and Chemoselectivity of Intramolecular Silyl Nitronate [3+2] Cycloadditions with Alkenyl/Alkynyl Nitroethers

This study examined the chemoselectivity and diastereoselectivity of silyl nitronate alkenyn-nitroethers in Intramolecular Silyl Nitronate Cycloadditions (ISNCs) to produce isoxazole derivatives with interesting medicinal properties. These reactions resulted in the formation of either dihydrofuro[3,...

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Bibliographic Details
Main Authors: Katelyn Stevens, Shik Ki Li, Emily Kaufman, Annika Schull, Katie Hassebroek, Joseph Stevens, Matthew Grandbois, Arlen Viste, Jetty Duffy-Matzner
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Molecules
Subjects:
PM6
dihydrofuro-2-isoxazolines
ISNC
alkenynyl nitroethers
3-(2,5-dihydrofuryl)carbonyls
chemoselectivity
Online Access:https://www.mdpi.com/1420-3049/29/24/5816
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