Effects of alkyl size of AlR3 on its reaction with thiophene-2-carbonyl chloride

Reactions of AlEt3, Al(n-Oct)3, and AlEt2(n-Oct) with thiophene-2-carbonyl chloride (TPCC) at Al/TPCC (molar ratio) <1 were respectively studied. The reaction produced ketone (ethyl thienyl ketone and/or n-octyl thienyl ketone) as the main product. The ketone yield reached the maximum after a ver...

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Bibliographic Details
Main Authors: Zhong Wentao, Yang Pengjia, Fu Zhisheng, Wang Qi, Fan Zhiqiang
Format: Article
Language:English
Published: De Gruyter 2025-04-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2023-0003
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