Pd/S cooperativity: from stoichiometric activation of Si−H bonds to catalytic hydrosilylation
Abstract With the aim to explore metal‐ligand cooperation across Pd−S linkages, we designed a quinoline‐based PNS tridentate ligand and prepared Pd(II) complexes thereof. Optimal solubility and stability of the dicationic complex [(PNS)Pd(II)]22+ IV2 were achieved with B(C6F5)4– as counter‐anion. It...
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| Main Authors: | Arnaud Clerc, Marceline Humbert, Sonia Mallet‐Ladeira, Dr. Karinne Miqueu, Dr. Julien Monot, Prof. Blanca Martín‐Vaca, Dr. Didier Bourissou |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2025-01-01
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| Series: | ChemistryEurope |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/ceur.202400079 |
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