Pd/S cooperativity: from stoichiometric activation of Si−H bonds to catalytic hydrosilylation

Pd/S cooperativity: from stoichiometric activation of Si−H bonds to catalytic hydrosilylation

Abstract With the aim to explore metal‐ligand cooperation across Pd−S linkages, we designed a quinoline‐based PNS tridentate ligand and prepared Pd(II) complexes thereof. Optimal solubility and stability of the dicationic complex [(PNS)Pd(II)]22+ IV2 were achieved with B(C6F5)4– as counter‐anion. It...

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Bibliographic Details
Main Authors: Arnaud Clerc, Marceline Humbert, Sonia Mallet‐Ladeira, Dr. Karinne Miqueu, Dr. Julien Monot, Prof. Blanca Martín‐Vaca, Dr. Didier Bourissou
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:ChemistryEurope
Subjects:
Homogeneous catalysis
Hydrosilylation
Metal/ligand cooperation
Palladium
Pincer ligand
Sulfur
Online Access:https://doi.org/10.1002/ceur.202400079
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https://doi.org/10.1002/ceur.202400079

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