Mn⊕-Induced Loss of Ethylene from Gaseous 4-Octyne
The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discusse...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1987-08-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9803 |
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| Summary: | The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discussed, and brief mentioning is also made on the propene loss which is unique to the [Mn(4-octyne)]⊕ complex.
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| ISSN: | 0009-4293 2673-2424 |