Mn⊕-Induced Loss of Ethylene from Gaseous 4-Octyne
The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discusse...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1987-08-01
|
| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9803 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|