Synthesis and Trapping of the Elusive <i>Ortho</i>-Iminoquinone Methide Derived from α-Tocopheramine and Comparison to the Case of α-Tocopherol

Synthesis and Trapping of the Elusive <i>Ortho</i>-Iminoquinone Methide Derived from α-Tocopheramine and Comparison to the Case of α-Tocopherol

Tocopheramines are a class of antioxidants which are distinguished from tocopherols (vitamin E) by the presence of an amino group instead of the phenolic hydroxyl group. α-Tocopheramine is intensively studied for biomedical applications but also as a stabilizer for synthetic and natural polymers, in...

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Bibliographic Details
Main Authors: Anjan Patel, Thomas Rosenau
Format: Article
Language:English
Published: MDPI AG 2025-08-01
Series:Molecules
Subjects:
tocopheramine
vitamin E
oxidation
<i>ortho</i>-iminoquinone methide
hetero-Diels–Alder reaction with inverse electron demand
spiro-dimerization
Online Access:https://www.mdpi.com/1420-3049/30/15/3257
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