Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions

This research analyzed the microstructure evolution, defect formation, and mechanical performance degradation mechanism of the bonding wire and Au-/Al interface with long-term exposure to 85 °C/85 %RH thermal-humidity bias (THB). The results showed that intermetallic compound (IMC) mainly appeared a...

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Main Authors: Yaru Wu, Qinsong Bi, Shumeng Lu, Hongfu Yang, Shanju Zheng, Xiaohong Yuan, Jiaheng Zhang, Xiaojing Wang, Mengnie Li
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425020708
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author Yaru Wu
Qinsong Bi
Shumeng Lu
Hongfu Yang
Shanju Zheng
Xiaohong Yuan
Jiaheng Zhang
Xiaojing Wang
Mengnie Li
author_facet Yaru Wu
Qinsong Bi
Shumeng Lu
Hongfu Yang
Shanju Zheng
Xiaohong Yuan
Jiaheng Zhang
Xiaojing Wang
Mengnie Li
author_sort Yaru Wu
collection DOAJ
description This research analyzed the microstructure evolution, defect formation, and mechanical performance degradation mechanism of the bonding wire and Au-/Al interface with long-term exposure to 85 °C/85 %RH thermal-humidity bias (THB). The results showed that intermetallic compound (IMC) mainly appeared at the Au-/Al interface, initially composed of AuAl and Au2Al, and transformed into Au4Al after THB, with a small amount of Au8Al3 phase present. The formation of IMC was attributed to the mutual diffusion of Au and Al. The wet heat environment accelerated the formation of IMC. The average thickness of IMC increased the fastest after 200 h THB. With the extension of the aging time, the growth rate of IMC gradually decreased, following the power function law. After THB, irregular particles containing Ag appeared on the surface of the Au wire, and the particles gradually moved from the second joint to the first joint as the aging continued. The mechanical performance results indicated that excessive IMCs, cracks, and voids at the interface deteriorated the mechanical properties of the Au wire bonds. The average maximum tensile force decreased by 62.42 %, and the average fracture energy also decreased by 49.35 %. The failure mode changed from wire fracture to bond ball detachment. This research explored the evolution of IMCs, element diffusion, and failure mechanism of bonding joints in the long-term wet heat environment, established the IMC growth rate equation and Au wire bonding electrochemical corrosion model, which is helpful for promoting further understanding in the field of metal wire bonding materials research and application.
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institution Kabale University
issn 2238-7854
language English
publishDate 2025-09-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj-art-1b325e4c467c486eb29ee97b10e146ce2025-08-24T05:12:51ZengElsevierJournal of Materials Research and Technology2238-78542025-09-01382978299110.1016/j.jmrt.2025.08.117Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditionsYaru Wu0Qinsong Bi1Shumeng Lu2Hongfu Yang3Shanju Zheng4Xiaohong Yuan5Jiaheng Zhang6Xiaojing Wang7Mengnie Li8Faculty of Material Science and Engineering, Yunnan Key Laboratory of Integrated Computational Materials Engineering for Advanced Light Alloys, Kunming University of Science and Technology, Kunming, 650093, ChinaYunnan Precious Metals Lab, Sino-Platinum Metals Co. Ltd., Kunming, 650106, ChinaFaculty of Material Science and Engineering, Yunnan Key Laboratory of Integrated Computational Materials Engineering for Advanced Light Alloys, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Material Science and Engineering, Yunnan Key Laboratory of Integrated Computational Materials Engineering for Advanced Light Alloys, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Material Science and Engineering, Yunnan Key Laboratory of Integrated Computational Materials Engineering for Advanced Light Alloys, Kunming University of Science and Technology, Kunming, 650093, China; Corresponding author.Yunnan Precious Metals Lab, Sino-Platinum Metals Co. Ltd., Kunming, 650106, China; Corresponding author.Jiangsu University of Science and Technology, Zhenjiang, 212003, ChinaJiangsu University of Science and Technology, Zhenjiang, 212003, China; Corresponding author.Faculty of Material Science and Engineering, Yunnan Key Laboratory of Integrated Computational Materials Engineering for Advanced Light Alloys, Kunming University of Science and Technology, Kunming, 650093, China; Corresponding author.This research analyzed the microstructure evolution, defect formation, and mechanical performance degradation mechanism of the bonding wire and Au-/Al interface with long-term exposure to 85 °C/85 %RH thermal-humidity bias (THB). The results showed that intermetallic compound (IMC) mainly appeared at the Au-/Al interface, initially composed of AuAl and Au2Al, and transformed into Au4Al after THB, with a small amount of Au8Al3 phase present. The formation of IMC was attributed to the mutual diffusion of Au and Al. The wet heat environment accelerated the formation of IMC. The average thickness of IMC increased the fastest after 200 h THB. With the extension of the aging time, the growth rate of IMC gradually decreased, following the power function law. After THB, irregular particles containing Ag appeared on the surface of the Au wire, and the particles gradually moved from the second joint to the first joint as the aging continued. The mechanical performance results indicated that excessive IMCs, cracks, and voids at the interface deteriorated the mechanical properties of the Au wire bonds. The average maximum tensile force decreased by 62.42 %, and the average fracture energy also decreased by 49.35 %. The failure mode changed from wire fracture to bond ball detachment. This research explored the evolution of IMCs, element diffusion, and failure mechanism of bonding joints in the long-term wet heat environment, established the IMC growth rate equation and Au wire bonding electrochemical corrosion model, which is helpful for promoting further understanding in the field of metal wire bonding materials research and application.http://www.sciencedirect.com/science/article/pii/S2238785425020708Au wire bondingAu–AlDouble 85 wet heat ageingIMCsMechanical property
spellingShingle Yaru Wu
Qinsong Bi
Shumeng Lu
Hongfu Yang
Shanju Zheng
Xiaohong Yuan
Jiaheng Zhang
Xiaojing Wang
Mengnie Li
Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
Journal of Materials Research and Technology
Au wire bonding
Au–Al
Double 85 wet heat ageing
IMCs
Mechanical property
title Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
title_full Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
title_fullStr Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
title_full_unstemmed Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
title_short Investigation into the evolution and failure mechanism of IMCs in Au wire bond interconnections under long-term wet heat conditions
title_sort investigation into the evolution and failure mechanism of imcs in au wire bond interconnections under long term wet heat conditions
topic Au wire bonding
Au–Al
Double 85 wet heat ageing
IMCs
Mechanical property
url http://www.sciencedirect.com/science/article/pii/S2238785425020708
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