X‐Ray Absorption Spectroscopy Probing of Gold Electro‐Oxidation Reveals Intermediate Surficial Au(I)

X‐Ray Absorption Spectroscopy Probing of Gold Electro‐Oxidation Reveals Intermediate Surficial Au(I)

While Au electro‐oxidation in acidic aqueous media on a phenomenological level proceeds directly from Au(0) to Au(III), it has previously been suggested that Au(I) states are intermediate species of the oxidation mechanism. Here, additional evidence for the transient Au(I) is provided by the probing...

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Bibliographic Details
Main Authors: David Degerman, Sara Boscolo Bibi, Bernadette Davies, Vladimir Grigorev, Aleksandr Kalinko, Tony Hansson, Sergey Koroidov
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:ChemElectroChem
Subjects:
Au oxidations
chlorination
high‐energy resolution fluorescence detected
intermediates
X‐ray absorption fine structures
Online Access:https://doi.org/10.1002/celc.202500127
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https://doi.org/10.1002/celc.202500127

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