Stereochemistry of the Carbon-Nitrogen Bond Cleavage by Chloroformate Esters
Nicotine reacts with chloroformic esters to give the chloro-carbamates resulting from the cleavage of the C2' –N1' bond. The reaction is shown to proceed with at least 96 to 98 % inversion of configuration. In the same way, (R)-(+)-N,N-dimethyl-α-phenethylamine gave (S)-(−)-α-phenethyl ch...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1974-11-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9188 |
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