One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation
Diaryl(iodo)bismuthanes possessing a hypervalent C=O•••Bi–I bond were conveniently synthesized in a one-pot reaction by using arylzinc reagents generated from o-carbonyl iodobenzenes and zinc powder under ultrasonication. This method is superior to the conventional organolithium and Grignard methods...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2019-01-01
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| Series: | Heteroatom Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2019/2385064 |
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| author | Toshihiro Murafuji A. F. M. Hafizur Rahman Daiki Magarifuchi Masahiro Narita Isamu Miyakawa Katsuya Ishiguro Shin Kamijo |
| author_facet | Toshihiro Murafuji A. F. M. Hafizur Rahman Daiki Magarifuchi Masahiro Narita Isamu Miyakawa Katsuya Ishiguro Shin Kamijo |
| author_sort | Toshihiro Murafuji |
| collection | DOAJ |
| description | Diaryl(iodo)bismuthanes possessing a hypervalent C=O•••Bi–I bond were conveniently synthesized in a one-pot reaction by using arylzinc reagents generated from o-carbonyl iodobenzenes and zinc powder under ultrasonication. This method is superior to the conventional organolithium and Grignard methods because it has a wide functional group tolerance, requires no protecting group manipulations, and proceeds under mild reaction conditions that do not need low temperature control. Furthermore, no intermediate triarylbismuthane precursor for the hypervalent iodobismuthane is necessary. |
| format | Article |
| id | doaj-art-155ae52e9bc3431d8490fbb3748f2ce6 |
| institution | Kabale University |
| issn | 1042-7163 1098-1071 |
| language | English |
| publishDate | 2019-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Heteroatom Chemistry |
| spelling | doaj-art-155ae52e9bc3431d8490fbb3748f2ce62025-08-20T03:54:25ZengWileyHeteroatom Chemistry1042-71631098-10712019-01-01201910.1155/2019/23850642385064One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by ZincationToshihiro Murafuji0A. F. M. Hafizur Rahman1Daiki Magarifuchi2Masahiro Narita3Isamu Miyakawa4Katsuya Ishiguro5Shin Kamijo6Graduate School of Sciences and Technology for Innovation, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Medicine, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Science and Engineering, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Sciences and Technology for Innovation, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Sciences and Technology for Innovation, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Sciences and Technology for Innovation, Yamaguchi University, Yamaguchi 753-8512, JapanGraduate School of Sciences and Technology for Innovation, Yamaguchi University, Yamaguchi 753-8512, JapanDiaryl(iodo)bismuthanes possessing a hypervalent C=O•••Bi–I bond were conveniently synthesized in a one-pot reaction by using arylzinc reagents generated from o-carbonyl iodobenzenes and zinc powder under ultrasonication. This method is superior to the conventional organolithium and Grignard methods because it has a wide functional group tolerance, requires no protecting group manipulations, and proceeds under mild reaction conditions that do not need low temperature control. Furthermore, no intermediate triarylbismuthane precursor for the hypervalent iodobismuthane is necessary.http://dx.doi.org/10.1155/2019/2385064 |
| spellingShingle | Toshihiro Murafuji A. F. M. Hafizur Rahman Daiki Magarifuchi Masahiro Narita Isamu Miyakawa Katsuya Ishiguro Shin Kamijo One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation Heteroatom Chemistry |
| title | One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation |
| title_full | One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation |
| title_fullStr | One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation |
| title_full_unstemmed | One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation |
| title_short | One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation |
| title_sort | one pot synthesis of hypervalent diaryl iodo bismuthanes from o carbonyl iodoarenes by zincation |
| url | http://dx.doi.org/10.1155/2019/2385064 |
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