One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation

Diaryl(iodo)bismuthanes possessing a hypervalent C=O•••Bi–I bond were conveniently synthesized in a one-pot reaction by using arylzinc reagents generated from o-carbonyl iodobenzenes and zinc powder under ultrasonication. This method is superior to the conventional organolithium and Grignard methods...

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Bibliographic Details
Main Authors: Toshihiro Murafuji, A. F. M. Hafizur Rahman, Daiki Magarifuchi, Masahiro Narita, Isamu Miyakawa, Katsuya Ishiguro, Shin Kamijo
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Heteroatom Chemistry
Online Access:http://dx.doi.org/10.1155/2019/2385064
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