Structural and Mechanistic Insights into the Metalation of Fluoroarenes Mediated by a Superbasic Co(II) Bis(amide) Complex

Over the past decades, s-block metal amides including LiTMP and TMPMgCl.LiCl (TMP = 2,2,6,6-tetramethylpiperidide) have found widespread applications in the deprotonative metalation of aromatic compounds. In contrast, transition metal amides usually exhibit diminished basicity to metalate these subs...

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Bibliographic Details
Main Authors: Na Jin, Eva Hevia
Format: Article
Language:deu
Published: Swiss Chemical Society 2025-04-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/7938
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