Electrophilic Catalysis in Iodosylbenzene Oxidation of Aromatic Derivatives

The oxidation of activated aromatic compounds (phenols and hydroquinones) is catalyzed by BF3 or RuCl2(PPh3)3. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species, in analogy to the effect of BF3. 

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Bibliographic Details
Main Authors: Paul Müller, David Manuel Gilabert
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-04-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9727
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