Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO

The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and Mössbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200ºC...

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Main Authors: Peltekov A.B., Boyanov B.S.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2013-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2013/1450-53391300037P.pdf
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author Peltekov A.B.
Boyanov B.S.
author_facet Peltekov A.B.
Boyanov B.S.
author_sort Peltekov A.B.
collection DOAJ
description The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and Mössbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200ºC and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed.
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publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-0b08e80569694de282651c146d93b6372025-02-02T18:23:57ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392013-01-0149333934610.2298/JMMB130624037P1450-53391300037PStudy of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgOPeltekov A.B.0Boyanov B.S.1University of Plovdiv “Paisii Hilendarski”, Department of Chemical Technology, Plovdiv, BulgariaUniversity of Plovdiv “Paisii Hilendarski”, Department of Chemical Technology, Plovdiv, BulgariaThe solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and Mössbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200ºC and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed.http://www.doiserbia.nb.rs/img/doi/1450-5339/2013/1450-53391300037P.pdfZnFe2O4Zn cakeCaOMgOXRD analysisMössbauer spectroscopyleaching
spellingShingle Peltekov A.B.
Boyanov B.S.
Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
Journal of Mining and Metallurgy. Section B: Metallurgy
ZnFe2O4
Zn cake
CaO
MgO
XRD analysis
Mössbauer spectroscopy
leaching
title Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
title_full Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
title_fullStr Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
title_full_unstemmed Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
title_short Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
title_sort study of solid state interactions in the systems znfe2o4 cao znfe2o4 mgo and zinc cake with cao and mgo
topic ZnFe2O4
Zn cake
CaO
MgO
XRD analysis
Mössbauer spectroscopy
leaching
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2013/1450-53391300037P.pdf
work_keys_str_mv AT peltekovab studyofsolidstateinteractionsinthesystemsznfe2o4caoznfe2o4mgoandzinccakewithcaoandmgo
AT boyanovbs studyofsolidstateinteractionsinthesystemsznfe2o4caoznfe2o4mgoandzinccakewithcaoandmgo