Single enantiomer propeller-shaped polynuclear complexes as catalysts-proof-of-concept for enantioinduction in a Michael addition reaction

Single enantiomer propeller-shaped polynuclear complexes as catalysts-proof-of-concept for enantioinduction in a Michael addition reaction

We report a family of propeller-shaped polynuclear metal complexes whose overall chirality is dictated by a single stereogenic centre within their component amino alcohol-ligand. These topologically intriguing complexes are readily prepared in enantiomerically pure form and are shown here to catalys...

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Bibliographic Details
Main Authors: Joe Maddocks, Mohan Mahesh, Stavroula I. Sampani, Alexander C. Dixon, Christian D.-T. Nielsen, Prashant Kumar, Geoffrey R. Akien, John Spencer, Alaa Abdul-Sada, John F. C. Turner, Alan C. Spivey, George E. Kostakis
Format: Article
Language:English
Published: The Royal Society 2025-03-01
Series:Royal Society Open Science
Subjects:
enantioselective induction
propeller-shaped complexes
Michael addition reaction
Online Access:https://royalsocietypublishing.org/doi/10.1098/rsos.241537
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https://royalsocietypublishing.org/doi/10.1098/rsos.241537

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