Der Mechanismus der Umlagerung substituierter Aminoacrylderivate II

The acid-catalysed reaction of 3-chloro-3-dimethylamino-propenal (2a, X=Cl), labelled at position 1 with 13C, yields 3-chloro-N,N-dimethyl-acrylamide (3a, X=Cl), containing the label exclusively at position 3. This result supports a mechanism including oxetenes as intermediates.

Saved in:
Bibliographic Details
Main Authors: M. Neuenschwander, A. Niederhauser
Format: Article
Language:deu
Published: Swiss Chemical Society 1973-07-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9094
Tags: Add Tag
No Tags, Be the first to tag this record!