Synthese und Eigenschaften von Tris(trifluormethylsulfonyl)amin

Tris(trifluoromethylthio)amine dissolved in pentane is oxidized by sodium hypochlorite at 0°C (3.5 h) to (CF3SO2)3N. Similarly the known (CF3SO2)2NNa is prepared from (CF3S)2NH. Actually (CF3SO2)3N is the first tertiary sulfonamide at all.

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Bibliographic Details
Main Authors: Alois Haas, Christiane Klare
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-03-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9724
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