[ReS4]⊖ as an Unusually Strong σ-Acceptor Ligand: [Cl2Fe(ReS4)FeCl2]2⊖, a Linear Heterometallic Cluster With an Odd Number of Electrons
[ReS4]⊖(Et4N⊕ salt) reacts with FeCl2 in the presence of (Ph4P)Cl in dichloromethane to give the first solid thiorhenato complex [Cl2Fe(ReS4)FeCl2]2⊖ as Ph4P⊕ salt, which contains a linear metal atom array with an odd number of electrons.
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1986-09-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9747 |
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