A Reexamination of CO2 Reduction with Fe2S2 Hydrogenase Mimics: Lessons in Using a Hydrogen Evolution Reaction Catalyst for CO2 to Formate Catalysis

A Reexamination of CO2 Reduction with Fe2S2 Hydrogenase Mimics: Lessons in Using a Hydrogen Evolution Reaction Catalyst for CO2 to Formate Catalysis

Recent reports show [FeFe] hydrogenase mimics are active for the electrochemical reduction of CO2 to formate (HCOO−). Herein, the electrochemical reduction of CO2 with the [FeFe] hydrogenase mimic [Fe2(μ‐pdt)(CO)6, 1, where pdt = propane‐1,3‐dithiolate] in acetonitrile is reported. In the presence o...

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Bibliographic Details
Main Authors: Christopher J. Miller, Byunghoon Lee, Jacob A. Barrett, Joseph M. Palasz, Thomas Chan, Anoushka Shandilya, Clifford P. Kubiak
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:ChemElectroChem
Subjects:
electrocatalysis
electrochemical reduction of CO2
hydrogen evolution reactions
transition metal hydrides
Online Access:https://doi.org/10.1002/celc.202500030
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https://doi.org/10.1002/celc.202500030

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