MoS2-confined Rh-Zn atomic pair boosts photo-driven methane carbonylation to acetic acid by Yanan Li, Huan Liu, Jun Mao, Meng Gao, Yunlong Zhang, Qiao Zhao, Meng Liu, Yao Song, Jingting Hu, Wangwang Zhang, Rui Huang, Wu Zhou, Kaifeng Wu, Wei Liu, Liang Yu, Xiaoju Cui, Dehui Deng

“…The active OH species produced from O2 photoreduction on the Zn site through proton-coupled electron transfer promotes CH4 dissociation to CH3 species, which then facilely couples with adsorbed CO on the adjacent Rh site forming the key CH3CO intermediate for CH3COOH formation.…”
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