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141
Tailored pc@zro₂@cellulose fiber composites as versatile materials for photocatalytic metal ion reduction and microbial deactivation
Published 2025-07-01“…The composite materials were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), N2 adsorption/desorption isotherms, and diffuse reflectance spectroscopy (DRS). The results revealed successful integration of the PCs with the ZrO2-cellulose matrix, facilitating efficient charge transfer and enhanced photocatalytic performance. …”
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142
Fe-TiO2 Nanoparticles Synthesized by Green Chemistry for Potential Application in Waste Water Photocatalytic Treatment
Published 2019-01-01“…The cathodoluminescence (CL) and photoluminescence (PL) studies of the doped and undoped nanoparticles show a luminescence signal attributed to surface oxygen vacancies (visible CL emission 380–700 nm and PL emission 350–800 nm); additionally, a decrease in emission intensity is observed due the inhibition of the recombination of the photogenerated electron-holes pairs; moreover, nanopowders were analyzed by UV-Vis spectrophotometry of diffuse reflectance, and the absorption edge of the Fe-TiO2 in comparison to undoped TiO2 is extended greatly toward the visible light. …”
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143
Surface and quantum chemical parameters of nickel oxide nanostructures suited for ultraviolet-assisted cationic dye degradation
Published 2024-04-01“…Fourier transform infrared spectroscopy and energy dispersive X-ray were employed to analyze the functional group and elemental composition of NiO NPs. The ultraviolet diffuse reflectance spectra indicated an optical band gap of 3.08 eV for synthesized NiO nanoparticles. …”
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144
Synthesis of Zinc Oxide-based nanocomposites for photocatalytic removal of contaminant
Published 2024-11-01“…The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FT-IR), and diffuse reflectance spectroscopy (DRS). The XRD results revealed that zinc oxide and graphite carbon nitride have a hexagonal wurtzite structure and a hexagonal structure, respectively. …”
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145
Towards controlling the morphology of cobalt loaded nanocomposites in polyol process with polyethylene glycol
Published 2023-12-01“…The PEG-based polyol process and the formation of cobalt nanophase were studied at molar ratios νCo2+/νOH(PEG) = 1:1, 1:10, 1:100 and 1:500 using UV-Vis, diffuse reflectance IR and ATR FT-IR spectroscopy, nanoparticle tracking analysis (NTA), dynamic light scattering (DLS). …”
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146
High-performance single-atom M/TiO2 catalysts in the reverse water-gas shift reaction: A comprehensive experimental and theoretical investigation
Published 2024-12-01“…Density functional theory (DFT) and in-situ diffuse reflectance infrared spectroscopy (DRIFTs) further explained that the atomically dispersed Ir sites in Ir/TiO2 follow a hydrogen-assisted mechanism, with the COOH* intermediate desorbing and dissociating into CO. …”
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147
Synthesis and Photocatalytic Activity of Mo-Doped TiO2 Nanoparticles
Published 2015-01-01“…The as-prepared samples were characterized by X-ray diffraction (XRD), diffuse reflectance UV-visible absorption spectra (UV-vis DRS), X-ray photoelectron spectra (XPS), and transmission electron microscopy (TEM). …”
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148
Radiative recombination model for BiSeI microcrystals: unveiling deep defects through photoluminescence
Published 2024-01-01“…Both indirect and direct band gap energies of BiSeI were determined by ultraviolet–visible–near-infrared diffuse reflectance spectroscopy, with room temperature values of 1.17 eV and 1.29 eV, respectively. …”
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149
Facile one-pot synthesis of photoresponsive Cu1.8S and CuInS2 nanostructures aided by Cu-pyrimidylthiolate molecular precursor
Published 2025-04-01“…Electron microscopic studies revealed the formation of polygonal and hexagonal morphology with varied size in Cu1.8S and CuInS₂ nanocrystals respectively. UV-Vis diffuse reflectance spectroscopy showed a slight blue shift in the band gap of the nanostructures compared to their bulk counterparts which can be attributed to quantum confinement or surface lattice distortion effects. …”
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150
Nigella Sativa-mediated Synthesis of BiVO4/g-C3N4 Composites for the Removal of Methylene Blue Dye
Published 2025-08-01“…The composites were synthesized using a coprecipitation method and characterized through various techniques, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), UV-Vis diffuse reflectance spectroscopy (DRS), Brunauer-Emmett-Teller (BET) surface area analysis, and scanning electron microscopy (SEM) to determine their crystal structure, chemical composition, morphology, adsorption and photocatalytic abilities. …”
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151
Facile Fabrication of CuO Modified TiO<sub>2</sub> Heterostructure for Enhanced Photocathodic Corrosion Protection of 304 Stainless Steel
Published 2025-06-01“…Surface characterization showed uniform, porous coatings with pore sizes ranging from 75 to 200 nm, which contributed to improved barrier properties. UV–visible diffuse reflectance spectroscopy (UV-DRS) demonstrated enhanced visible light absorption in the heterostructures. …”
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152
Two-Dimensional Lamellar Stacked Bi<sub>2</sub>O<sub>3</sub>/CeO<sub>2</sub> Type-II Heterojunctions Promote Carrier Separation to Enhance Ciprofloxacin Oxidation
Published 2025-04-01“…Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) analyses confirmed the uniform distribution of Bi<sub>2</sub>O<sub>3</sub> nanosheets on CeO<sub>2</sub> surfaces, forming an intimate interfacial contact that enhances charge separation and transfer efficiency. Photoluminescence (PL) spectroscopy, UV–visible diffuse reflectance spectroscopy (DRS), and electrochemical characterization revealed extended visible-light absorption (up to 550 nm) and accelerated electron migration in the heterojunction. …”
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153
Comparison of Photocatalytic Activity: Impact of Hydrophilic Properties on TiO<sub>2</sub> and ZrO<sub>2</sub> Thin Films
Published 2024-12-01“…The band gap (BG) energies, as calculated from UV-Vis spectroscopy and diffuse reflectance spectroscopy, corresponded to 3.2 and 3.7 eV for the TiO<sub>2</sub> and ZrO<sub>2</sub> TFs, respectively. …”
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154
Effect of Subgrains on the Performance of Mono-Like Crystalline Silicon Solar Cells
Published 2013-01-01“…These subgrains have an almost negligible effect on the optical performance, shunt resistance, and junction recombination but significantly affect the minority carrier diffusion length and quantum efficiency within a long wavelength range. …”
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155
Sodium cation exchanged zeolites for direct air capture of CO2
Published 2025-01-01“…This study systematically investigated the CO2 adsorption-desorption performance of the representative zeolites (ZSM-5, Beta, Mordenite and Y) in H- and Na-forms using various analytical methods, including in-situ Diffuse Reflectance Infrared Fourier Transform spectroscopy. …”
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156
Degradation of bisphenol A using a MOF@COF-modified polyacrylonitrile ultrafiltration membrane
Published 2025-08-01“…The composite was successfully synthesised using solvothermal synthesis and structurally analysed via XRD and FTIR, confirming crystal structure and covalent bonding between MIL-101-NH₂ and TpMA via the adsorption bands detected at 765 and 1247-1257 cm−1 (N-H wagging band and C-N stretching bands). UV–vis diffuse reflectance analysis revealed a narrowed band gap upon hybridisation (0.92 eV) signifying enhanced photocatalytic activity, while photoluminescence spectra indicated reduced electron–hole recombination. …”
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157
Structural Insights into Ni‐Stabilized Fe‐Rich High‐Voltage Spinels: LiNixFe0.5−xMn1.5O4
Published 2025-08-01“…The cycling mechanism of LiFe0.5Mn1.5O4 and Ni‐stabilized LiNi0.2Fe0.3Mn1.5O4 is further compared via in situ powder X‐ray diffraction and in situ diffuse reflectance infrared Fourier transform spectroscopy. …”
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158
Pulsed reverse electrochemical synthesis of Ag-TiO2 composites from deep eutectic solvents: Photocatalytic and antibacterial behaviour
Published 2025-06-01“…TEM analysis revealed that silver nanoparticles (Ag NPs) are attached to TiO2 nanopowder, with the coexistence of TiO2 and Ag further confirmed by XRD and XPS. The recorded UV–Vis diffuse reflectance spectra (DRS) displayed a broad peak in the range of 400 – 650 nm, associated with the localized surface plasmon resonance (LSPR) of Ag NPs on the semiconductor’s surface. …”
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159
Novel CaCO3/g-C3N4 composites with enhanced charge separation and photocatalytic activity
Published 2019-12-01“…The as-prepared samples were characterized using various techniques, such as scanning and transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller analysis, as well as Fourier-transform infrared, X-ray photoelectron, photoluminescence, and UV–vis diffuse reflectance spectroscopy. The results of the experiments confirm the successful coupling of CaCO3 to g-C3N4. …”
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160