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Controllable Strategy of Metal–Organic Framework Structural Stability: Regulation of Ligand Electronegativity by Esterification
Published 2025-01-01“…The hydroxyl groups are esterified to obtain ester groups with stronger electronegativity, which can weaken the strength of coordination between metal ion and ligand, thereby regulating the structure stability of the Zr‐MOF. …”
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ANALYSIS OF AIR QUALITY IN TELEORMAN BY MEANS OF BIOMONITORS-LICHENS
Published 2023-05-01Subjects: Get full text
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Heavy metals accumulation in lichens Parmeliaceae and mahogany bark as an indicator of air and pollution levels in several locations in Bandung City
Published 2024-05-01“…Objective: This study aims to determine the concentration of heavy metals accumulated in lichens and tree bark across various locations in Bandung City, analyze the impact of heavy metal accumulation on lichen diversity, and assess the lichen cover area on tree bark. …”
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Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine
Published 2013-01-01“…An IR spectrum indicates that the ligand behaves as bidentate ligands. The metal complexes have been screened for their antifungal activity towards Aspergillus niger fungi. …”
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Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
Published 2011-01-01“…The binding property of metal ions was performed and maximum sorption capacity of the copper was 3.20 mmol/ g and the rate of exchange of some metals was faster, i.e. t½ ≈ 7 min (average). …”
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Synthesis, Characterization, Biological Activity and DNA Binding Studies of Metal Complexes with 4-Aminoantipyrine Schiff Base Ligand
Published 2012-01-01“…A new series of transition metal complexes of Cu(II),Ni(II),Co(II), Zn(II) and VO(IV) have been synthesized from the Schiff base ligand (L) derived from 4-amino antipyrine and 5- bromo salicylaldehyde. …”
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Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
Published 2010-01-01“…The flexible ditopic ligand 3,3-bipyridine (3,3-bpy) has been reacted with a series of transition metal species (Ag+, Hg2+, cis-a2M2+ (a=NH3 or a2=en; M=Pt,Pd), trans-a2Pt2+ (a=NH3)) in an attempt to produce discrete cyclic constructs. …”
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Pressure treatment enables white-light emission in Zn-IPA MOF via asymmetrical metal-ligand chelate coordination
Published 2025-01-01“…Here, we achieve a high-performance white-light emission with photoluminescence quantum yield of 81.3% via boosting triplet excitons distribution through pressure treatment in single-component Zn-IPA metal-organic frameworks. A novel metal-ligand asymmetrical chelate coordination is successfully integrated into the Zn-IPA after a high-pressure treatment over ~20.0 GPa. …”
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Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes
Published 2013-01-01“…The mixed ligand transition metal complexes of 4-N,N-dimethylaminopyridine (DP) and chloride as primary and secondary ligands with the general formula [M(DP)3Cl3]; M = Cr(III) and Fe(III); [M′(DP)4Cl2]M′ = Co(II), Ni(II), Cu(II), and Cd(II) were synthesized in a microwave oven. …”
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An efficient transition-metal-free route to oligo-$\alpha $-pyridylamines via fluoroarenes
Published 2023-03-01Subjects: Get full text
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Cu66 nanoclusters from hierarchical square motifs: Synthesis, assembly, and catalysis
Published 2025-01-01Subjects: Get full text
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Masking Ability of Various Metal Complexing Ligands at 1.0 mM Concentrations on the Potentiometric Determination of Fluoride in Aqueous Samples
Published 2020-01-01“…In most of the reported literature, higher concentrations of strong metal chelating ligands are used as masking agents generally in the concentration range of 1.0 to 0.01 M. …”
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NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY
Published 2017-09-01“…The environment around the metallic centers is octahedral or square pyramidal. …”
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Distribution characteristics and pollution assessment of heavy metals in typical black soil profiles of Haicheng city, Liaoning province, China.
Published 2025-01-01“…In order to understand the spatial distribution, influencing factors, pollution level and sources of heavy metals in black soil profiles in Northeast China, black soil profile samples were collected from five sampling points in Haicheng City, Liaoning Province, with the deepest profile depth of 50m. …”
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‘Alexa, play metal’: exploring music selection and personal information management via voice assistants
Published 2024-06-01Get full text
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Synthesis, Characterization and Antifungal Activity of Novel Quinazolin-4-one Derivatives Containing 8-Hydroxyquinazoline Ligand and its Various Metal Complexes
Published 2009-01-01“…Both the compounds were designated respectively as HL1 and HL2 ligands. The transition metal (Cu2+, Ni2+, Zn2+, Mn2+ and Co2+) complexes of both these ligands were prepared. …”
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An unusual chiral-at-metal mechanism for BINOL-metal asymmetric catalysis
Published 2025-01-01“…Their chiral induction mode, however, typically relies on multifarious non-covalent interactions between the substrate and the BINOL ligand. In this work, we demonstrate that the chiral-at-metal stereoinduction mode could serve as an alternative mechanism for BINOL-metal catalysis, based on mechanistic studies of BINOL-aluminum-catalyzed asymmetric hydroboration of heteroaryl ketones. …”
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