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    Protection without poison: why tropical ozone maximizes in the interior of the atmosphere by A. Match, E. P. Gerber, S. Fueglistaler

    Published 2025-04-01
    “…Textbooks explain this interior maximum with two paradigms: (1) the <i>source-controlled paradigm</i> explains <span class="inline-formula">[O<sub>3</sub>]</span> as maximizing where its source maximizes between abundant photons aloft and abundant <span class="inline-formula">[O<sub>2</sub>]</span> below, and (2) the <i>source</i> <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M4" display="inline" overflow="scroll" dspmath="mathml"><mo>/</mo></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="8pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="57ee8123d9c9aefcf23d9c7f6463c158"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-25-4349-2025-ie00001.svg" width="8pt" height="14pt" src="acp-25-4349-2025-ie00001.png"/></svg:svg></span></span> <i>sink competition paradigm</i>, inspired by the Chapman cycle, explains ozone as scaling with <span class="inline-formula">[O<sub>2</sub>]</span> and the photolytic source <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M6" display="inline" overflow="scroll" dspmath="mathml"><mo>/</mo></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="8pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="073414a2b77546d8d5847ae97897d626"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-25-4349-2025-ie00002.svg" width="8pt" height="14pt" src="acp-25-4349-2025-ie00002.png"/></svg:svg></span></span> sink ratio. …”
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