Gamma Radiolysis Studies of Aqueous Solution of Brilliant Green Dye by D. V. Parwate, S. S. Mankar

“…This may be attributed to the presence of reaction by-products from the destruction of parent compound build up and compete for reaction intermediate species. The rate of reaction and rate constants were calculated and it was found that the degradation reaction follows first order kinetics. …”
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Numerical Investigation of Inlet Thermodynamic Conditions on Solid Fuel Ramjet Performances by Weixuan Li, Dan Zhao, Xiong Chen, Liang Zhu, Siliang Ni

“…Furthermore, the analysis on the chemical reaction intermediate (CO) reveals that the chemical reaction is more sufficient with increased ṁair, but SN=0. …”
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Theoretical understanding of water splitting by analyzing nanocatalyst photoabsorption spectra by Gollapalli Prince, Caspary Toroker Maytal

“…For instance, the signature of the dominant absorption peak at 580 nm in the observed spectra of Fe2O3 photoanode can shed light on the oxygen evolution reaction mechanism since each reaction intermediate affects the absorption spectrum, and the absorption coefficient in turn affects the photocurrent. …”
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Characterization of Cu(II)-ACC Complexes and Conversion of the Bound ACC into Ethylene in the Presence of Hydrogen Peroxide. Detection of a Brown Intermediate at Low Temperature by Wadih Ghattas, Michel Giorgi, Christian Gaudin, Antal Rockenbauer, Marius Réglier, A. Jalila Simaan

“…The presence of an exogenic ligand (bpy) is important for the reactivity and may stabilize a reaction intermediate. Indeed, a brown intermediate with an absorption band centered at 433 nm can be detected at low temperature when 1 is treated with 10 equivalents of H2O2.…”
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Stereoelectronic Effect of Protecting Groups on the Stability of Galactosyl Donor Intermediates by Ryan W. Kwok, Ryan Rutkoski, Pavel Nagorny, Mateusz Marianski

“…Using methods of DFT, we investigated the effect of electron withdrawing and electron donating groups on the relative stability of tentative glycosyl donor reaction intermediates. The calculation shows that by changing the stereoelectronic properties of the protecting group, we can influence the stability of the dioxolenium type of intermediates by up to 10 kcal mol⁻¹, and that by increasing nucleophillicity of the 4-<i>O</i>-Bz group, the dioxolenium intermediate becomes more stable than a triflate–donor pair. …”
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Transient pulsed discharge preparation of graphene aerogel supports asymmetric Cu cluster catalysts promote CO2 electroreduction by Kaiyuan Liu, Hao Shen, Zhiyi Sun, Qiang Zhou, Guoqiang Liu, Zhongti Sun, Wenxing Chen, Xin Gao, Pengwan Chen

“…We elucidate the key reaction intermediates and mechanisms on Cu4O-Cu/C2O1 moieties through in situ testing and density functional theory calculations. …”
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Yttrium-doped NiMo-MoO2 heterostructure electrocatalysts for hydrogen production from alkaline seawater by Shujie Liu, Zhiguo Zhang, Kamran Dastafkan, Yan Shen, Chuan Zhao, Mingkui Wang

“…However, precisely controlling the interaction between electrocatalysts and reaction intermediates (H2O*, H*, and *OH) remains challenging. …”
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Densely populated macrocyclic dicobalt sites in ladder polymers for low-overpotential oxygen reduction catalysis by Zhen Zhang, Zhenyu Xing, Xianglin Luo, Chong Cheng, Xikui Liu

“…In situ techniques and theoretical calculations reveal the dynamic evolution of Co2N4O2 active sites and reaction intermediates. In alkaline conditions, the catalyst exhibits impressive oxygen reduction reaction activity featuring an onset potential of 1.10 V and a half-wave potential of 1.00 V, insignificant decay after 30,000 cycles, pushing the overpotential boundaries of ORR electrocatalysis to a low level. …”
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Antibacterial and antioxidant potentials, detection of host origin compounds, and metabolic profiling of endophytic Bacillus spp. isolated from Rauvolfia serpentina (L.) Benth. ex... by Rusi Lata, Surendra Kumar Gond

“…UHPLC-HRMS profiling unveiled a diverse range of host-derived compounds and reaction intermediates with known and unknown bioactive properties in leaf extract, RSLB3, and RSLB18. …”
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In Situ Modulation of NiFeOOH Coordination Environment for Enhanced Electrocatalytic‐Conversion of Glucose and Energy‐Efficient Hydrogen Production by Ning Wei, Sufeng Zhang, Xue Yao, Qinglu Li, Nan Li, Jinrui Li, Dingjie Pan, Qiming Liu, Shaowei Chen, Scott Renneckar

“…Notably, electrochemical activation of W‐NiFeP facilitates the in situ formation of phosphate groups producing W,P‐NiFeOOH, which, in conjunction with the W co‐doped amorphous layers, leads to a high electrocatalytic performance toward GCR, due to enhanced proton transfer and adsorption of reaction intermediates, as confirmed in experimental and theoretical studies. …”
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