Diazotrophs: An Overlooked Sink of N2O

Abstract The ocean is the second‐largest source of greenhouse gas nitrous oxide (N2O). However, its role as an N2O sink is severely overlooked. N2O fixation by diazotrophs has lately been proposed as a new pathway of N2O consumption. We investigated diazotrophic N2O consumption and examined the anth...

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Main Authors: Himanshu Saxena, Shreya Mehta, Sipai Nazirahmed, Jitender Kumar, Sanjeev Kumar, Arvind Singh
Format: Article
Language:English
Published: Wiley 2025-03-01
Series:Geophysical Research Letters
Subjects:
Online Access:https://doi.org/10.1029/2024GL114117
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author Himanshu Saxena
Shreya Mehta
Sipai Nazirahmed
Jitender Kumar
Sanjeev Kumar
Arvind Singh
author_facet Himanshu Saxena
Shreya Mehta
Sipai Nazirahmed
Jitender Kumar
Sanjeev Kumar
Arvind Singh
author_sort Himanshu Saxena
collection DOAJ
description Abstract The ocean is the second‐largest source of greenhouse gas nitrous oxide (N2O). However, its role as an N2O sink is severely overlooked. N2O fixation by diazotrophs has lately been proposed as a new pathway of N2O consumption. We investigated diazotrophic N2O consumption and examined the anthropogenic influence on N2O dynamics in the coastal northeastern Arabian Sea, a hotspot of N2O emissions. Our findings reveal that relatively unperturbed waters, unlike anthropogenically perturbed waters, are a modest net N2O sink (98 ± 29% saturation), contrary to previous reports. N2O fixation remains active in anthropogenically perturbed waters in contrast to N2 fixation. We additionally provide evidence that the absence of control incubations leads to incorrect fixation rate estimates, further implying that oceanic dark carbon fixation rates might be overestimated. We suggest that N2O fixation not only directly sequesters N2O but may correspond to 0.3 Tg C y−1 of global ocean net primary production.
format Article
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institution Kabale University
issn 0094-8276
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language English
publishDate 2025-03-01
publisher Wiley
record_format Article
series Geophysical Research Letters
spelling doaj-art-fffe68c851974e86a6496ca989d6486f2025-08-20T03:52:32ZengWileyGeophysical Research Letters0094-82761944-80072025-03-01526n/an/a10.1029/2024GL114117Diazotrophs: An Overlooked Sink of N2OHimanshu Saxena0Shreya Mehta1Sipai Nazirahmed2Jitender Kumar3Sanjeev Kumar4Arvind Singh5Geosciences Division Physical Research Laboratory Ahmedabad IndiaGeosciences Division Physical Research Laboratory Ahmedabad IndiaGeosciences Division Physical Research Laboratory Ahmedabad IndiaGeosciences Division Physical Research Laboratory Ahmedabad IndiaGeosciences Division Physical Research Laboratory Ahmedabad IndiaGeosciences Division Physical Research Laboratory Ahmedabad IndiaAbstract The ocean is the second‐largest source of greenhouse gas nitrous oxide (N2O). However, its role as an N2O sink is severely overlooked. N2O fixation by diazotrophs has lately been proposed as a new pathway of N2O consumption. We investigated diazotrophic N2O consumption and examined the anthropogenic influence on N2O dynamics in the coastal northeastern Arabian Sea, a hotspot of N2O emissions. Our findings reveal that relatively unperturbed waters, unlike anthropogenically perturbed waters, are a modest net N2O sink (98 ± 29% saturation), contrary to previous reports. N2O fixation remains active in anthropogenically perturbed waters in contrast to N2 fixation. We additionally provide evidence that the absence of control incubations leads to incorrect fixation rate estimates, further implying that oceanic dark carbon fixation rates might be overestimated. We suggest that N2O fixation not only directly sequesters N2O but may correspond to 0.3 Tg C y−1 of global ocean net primary production.https://doi.org/10.1029/2024GL114117N2 fixationN2O fixationgreenhouse gasesprimary productionArabian seaNitrogen cycle
spellingShingle Himanshu Saxena
Shreya Mehta
Sipai Nazirahmed
Jitender Kumar
Sanjeev Kumar
Arvind Singh
Diazotrophs: An Overlooked Sink of N2O
Geophysical Research Letters
N2 fixation
N2O fixation
greenhouse gases
primary production
Arabian sea
Nitrogen cycle
title Diazotrophs: An Overlooked Sink of N2O
title_full Diazotrophs: An Overlooked Sink of N2O
title_fullStr Diazotrophs: An Overlooked Sink of N2O
title_full_unstemmed Diazotrophs: An Overlooked Sink of N2O
title_short Diazotrophs: An Overlooked Sink of N2O
title_sort diazotrophs an overlooked sink of n2o
topic N2 fixation
N2O fixation
greenhouse gases
primary production
Arabian sea
Nitrogen cycle
url https://doi.org/10.1029/2024GL114117
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AT shreyamehta diazotrophsanoverlookedsinkofn2o
AT sipainazirahmed diazotrophsanoverlookedsinkofn2o
AT jitenderkumar diazotrophsanoverlookedsinkofn2o
AT sanjeevkumar diazotrophsanoverlookedsinkofn2o
AT arvindsingh diazotrophsanoverlookedsinkofn2o